Physical and Chemical Characterization of Agricultural Waste and Testing of Sorbtion Abilities for Removal of Heavy Metals from Aqueous Solutions

  • Indira Šestan
  • Melisa Ahmetović
  • Amra Odobašić
  • Amra Bratovčić
  • Sabina Begić
Keywords: Cadmium, Nickel, Physical and chemical characterization, Sorption


The problem of environmental pollution is more expressed and more present by the development of the industry and the growth of the human population. Pollution of natural and wastewater is most often due to the release of heavy metals into watercourses. The greatest challenge for researchers is choosing the right biomass from a large number of low-cost biomaterials, and availability and price are very important selection factors. Microbial biomass, forestry waste and agroindustrial complexes are most frequently examined, as well as various macromolecules of natural origin. In this paper, barley straw that arises as agricultural waste product in barley production in Bosnia and Herzegovina, was used as a biosorbent. In the experimental part, physical and chemical characterization of  barley straw was performed, after which the efficiency of removing Cd(II) and Ni(II) from aqueous solutions, using barley straw, and the influence of process parameters (pH value of aqueous solution, biosorbent size, interaction of metal ions) on the biosorption capacity were tested. It can be concluded that barley straw has good adsoption characteristics for the use as a low-cost natural sorbent for the removal of heavy metals from water.


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Cornelis, R.; Crews, H.; Caruso, J. and Heumann, K. (eds). (2005). Handbook of elemental speciation II: Species in the environment, food, medicine and occupational health. Chichester: John Wiley and Sons.

Mudhoo, A.; Garg, V.K. and Wang, S. (2012). Removal of heavy metals by biosorption. Environmental Chemistry Letters, 10(2), 109-117.

Đorđević., S. and Dražić, V. (2010). Fizička hemija. Beograd: TMF.

Ahluwalia, S.S. and Goyal, D. (2007). Microbial and plant derived biomass for removal of heavy metals from wastewater. Bioresource Technology, 98(12), 2243-2257.

Šćiban, M. (2013). Biosorpcija teških metala iz vode. Novi Sad: Tehnološki fakultet.

Bilal, M.; Shah, J.A.; Ashafaq, T.; Gardazi, S.M.H.; Tahir, A.A.; Pervez, A.; Haroon, H. and Mahmood, Q. (2013). Waste biomass adsorption for copper removal from industrial wastewater: A review. Journal of Hazardous Materials, 263 Pt 2, 322-333.

Babarinde, N.A.A.; Babalola, J.O. and Sanni, R.A. (2006). Biosorption of lead ions from aqueous solution by maize leaf. International Journal of. Physical Sciences, 1(1) 23-26.

Babarinde, N.A.A.; Babalola, J.O. and Adetunji, A.A. (2008). Isotherm and Thermodynamic Studies of the Biosorption of Zinc (II) from Solution by Maize Leaf. The Pacific Journal of Science and Technology, 9(1), 196-202.

Babarinde, N.A.A.; Babalola, J.O. and Sanni, S.O. (2007). Isotherm and thermodynamic studies of the biosorption of Cd(II) from solution by maize leaf. International Journal of Physical Sciences, 2(8), 207-211.

Suantak, K.; Chandrajit, B. and Shri, C. (2011). Removal of As (III) from Aqueous Solution by Biosorption onto Maize (Zea mays) Leaves Surface: Parameters Optimization Sorption Isotherm, Kinetic and Thermodynamics Studies. Research Journal of Chemical Sciences, 1(5), 73-79.

Prabha, R.T. and Udayashankara, T.H. (2014). Removal of heavy metal from synthetic wastewater using Rice husk and Groundnut shell as adsorbents. IOSR Journal of Environmental Science, Toxicology and Food Technology, 8(7), 26-34.

El–Moselhy, K.M.; Abdel-Azzem, M.; Amer, A. and Al-Prol, A.E. (2017). Adsorption of Cu(II) and Cd(II) from Aqueous Solution by Using Rice Husk Adsorbent. Physical Chemistry: An Indian Journal, 12(2), 109-122.

Al-Baidhani, J.H. and Al-Salihy, S.T. (2016). Removal of Heavy Metals from Aqueous Solution by Using Low Cost Rice Husk in Batch and Continuous Fluidized Experiments. International Journal of Chemical Engineering and Applications, 7(1), 6-10.

Muneer, M.; Bhatti, I.A. and Adeel, S. (2010). Removal of Zn, Pb and Cr in Textile Wastewater Using Rice Husk as a Biosorbent. Asian Journal of Chemistry, 22(10), 7453-7459.

Wolfova, R.; Pertile, E. and Fečko, P. (2013). Removal of lead from aqueous solution by walnut shell. Journal of Environmental Chemistry and Ecotoxicology, 5(6), 159-167.

Altun, T. and Pehlivan, E. (2007). Removal of copper(II) ions from aqueous solutions by walnut, hazelnut and almond shells. Clean – Soil. Air, Water, 35(6), 601–606.

Orhan, Y. and Büyükgüngör, H. (1993). The removal of heavy metals by using agricultural wastes. Water Science and Technology, 28(2), 247-255.

Ilyas, M.; Ahmad, A. and Saeed, M. (2013). Removal of Cr (VI) from Aqueous Solutions Using Peanut shell as Adsorbent. Journal of the Chemical Society of Pakistan, 35(3), 760-768.

Rocha, A.; Zaia, D.A. and Alfaya, R.V. (2009). Use of rice straw as biosorbent for removal of Cu(II), Zn(II), Cd(II) and Hg(II) ions in industrial effluents. Journal of Hazardous Materials, 166(1), 383–388.

Jia, D. and Li, C. (2015). Adsorption of Pb(II) from aqueous solutions using corn straw. Desalination and Water Treatment, 56(1), 223-231.

Song, D.; Pan, K.; Tariq, A.; Azizullah, A.; Sun, F.; Li, Z. and Xiong, Q. (2016). Adsorptive Removal of Toxic Chromium from Waste-Water Using Wheat Straw and Eupatorium Adenophorum. PloS one, 11(12):e0167037

Larsen, V.J. and Schierup, H.H. (1981). The Use of Straw for Removal of Heavy Metals from Waste Water. Journal of Environmental Quality Abstract, 10(2), 188-193.

Acharya, J.; Kumar, U. and Rafi, P.M. (2018). Removal of Heavy Metal Ions from Wastewater by Chemically Modified Agricultural Waste Material as Potential Adsorbent-A Review. International Journal of Current Engineering and Technology, 8(3), 526-530.

Pehlivan, E.; Altun, T.; Cetin, S. and Bhanger, M.I. (2009). Lead sorption by waste biomass of hazelnut and almond shell. Journal of Hazardous Materials, 167(1-3), 1203–1208.

How to Cite
Indira Šestan, Melisa Ahmetović, Amra Odobašić, Amra Bratovčić, & Sabina Begić. (2018). Physical and Chemical Characterization of Agricultural Waste and Testing of Sorbtion Abilities for Removal of Heavy Metals from Aqueous Solutions. International Journal for Research in Applied Sciences and Biotechnology, 5(6), 1-8.

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