Efficiency of Carbonate Precipitation and Removal of Copper and Nickel Ions from their Monocomponent and Two-component Aqueous Solutions

  • Halid Junuzović
  • Sabina Begić
  • Amra Selimović
  • Abdel Đozić
  • Ramzija Cvrk
  • Melisa Ahmetović
Keywords: Carbonate Precipitation, Water Treatment, Na2CO3, Copper, Nickel

Abstract

The effect of pH and initial concentration on the removal of Cu(II) and Ni(II) ions from their monocomponent and two-component aqueous solutions using Na2CO3 as a chemical precipitation agent was investigated in this paper. Monocomponent aqueous solutions  of Cu(II) and Ni(II)  ions with their initial concentrations of 50 and 500 mg/L and two-component aqueous solution with initial concentration of 500 mg/L were prepared. The precipitation was carried out by batch method at room temperature by stirring the solution at 300 rpm for 5 minutes, resulting in the formation of precipitates. The resulting precipitate was separated by filtration from the solution. The experiment proved that Na2CO3 is a good agent for removing Cu(II) and Ni(II) ions from their monocomponent water solutions of 50 and 500 mg/L concentration and two-component water solution with initial concentration of each metal 500 mg/L. The percentage of Cu(II) removal was higher at lower pH values compared to Ni(II) removal.

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References

S. M. Kleiner. (1999). Water: an essential but overlooked nutrient. Journal of the Academy of Nutrition and Dietetics, 99(2), 200-206.

Ibukun Modupe Adesiyan, Mary Bisi-Johnson, Omolara Titilayo Aladesanmi, Anthony I Okoh & Aderemi Okunola Ogunfowokan. (2018). Concentrations and human health risk of heavy metals in rivers in southwest nigeria. Journal of Health & Pollution, 8(19), 180907.

doi: 10.5696/2156-9614-8.19.180907

F.X.Rvan Leeuwen. (2000). Safe drinking water: the toxicologist's approach. Food and Chemical Toxicology, 38(1), S51-S58.

Abdel-Raouf MS & Abdul-Raheim ARM. (2016). Removal of heavy metals from industrial waste water by biomass-based materials: a review. Journal of Pollution Effects & Control, 5(1), 1-13.

Meihua Zhao, Ying Xu, Chaosheng Zhang, Hongwei Rong & Guangming Zeng. (2016). New trends in removing heavy metals from wastewater. Applied Microbiology and Biotechnology, 100(15), 6509-6518.

John Duffus. (2002). Heavy metals” a meaningless term? (IUPAC Technical Report). Pure and Applied Chemistry, 74(5), 793-807.

G. Al-Enezi, M. F. Hamoda & N. Fawzi. (2011). Ion exchange extraction of heavy metals from wastewater sludges. Journal of Environmental Science and Health, Part A (Toxic/Hazardous Substances and Environmental Engineering). 39(2), 455-464.

doi: 10.1081/ESE-120027536

Hani Abu-Qudais & Hassan Moussa. (2004). Removal of heavy metals from wastewater by membrane processes: a comparative study. Desalination, 164(2), 105-110.

doi: 10.1016/S0011-9164(04)00169-9

Vhahangwele Masindi and Khathutshelo L. Muedi. (2018). Environmental Contamination by Heavy Metals. In: Intech Open. UK..

C. Femina Carolin, P. Senthil Kumar, A. Saravanan, G. Janet Joshiba & Mu. Naushad. (2017). Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review. Journal of Environmental Chemical Engineering, 5(3), 2782-2799.

Arezoo Azimi, Mashallah Rezakazemi, Ahmad Azari & Meisam Ansarpour. (2017). Removal of heavy metals from industrial wastewaters: a review. ChemBioEng Reviews, 4(1), 37-59.

doi: 10.1002/cben.201600010

Lotfi Monser, Nafaâ Adhoum. (2002). Modified activated carbon for the removal of copper, zinc, chromium and cyanide from wastewater. Separation and Purification Technology, 26(2-3), 137-146.

Wang L.K., Vaccari D.A., Li Y., Shammas N.K. (2005). Chemical Precipitation. In: Physicochemical Treatment Processes. Handbook of Environmental Engineering, (vol 3). Humana Press.

Dr. Huan-I Hung. (2016). Current methods for removing heavy metals from industrial wastewater. Manufacturing.net.

Available at: https://www.manufacturing.net/operations/blog/13126178/current-methods-for-removing-heavy-metals-from-industrial-wastewater

Svetlana B. Z. (2018). Current legislation and methods of treatment of wastewater coming from waste electrical and electronic equipment processing. In: Water Electrical and Electronic Equipment Recycling: Aqueous Recovery Methods. Woodhead Publishing.

Michael Ojovan,William Lee & Stepan Kalmykov. (2019). Treatment of Radioactive Wastes. In: An Introduction to Nuclear Waste Immobilisation (3rd.ed.). Elsevier.

Peters R.W. & Shem L. (1993). Separation of heavy metals: Removal from industrial wastewaters and contaminated soil. International conference on emerging separation technologies for metals and fuels, Palm Coast. Argonne National Lab., IL (United States). Energy Systems Div., 13-28.

Habib Karimi. (2017). Effect of pH and Initial pb(II) Concentration on The Lead Removal Efficiency from Industrial Wastewater Using Ca(OH)2 . International Journal of Water and Wastewater Treatment. 3(2), 1-4.

doi: 10.16966/2381-5299.139

Yaser Dahman. (2017). Nanopolymers. In: Nanotechnology and Functional Materials for Engineers, (1st ed.). Elsevier.

Kelts K., Hsü K.J. (1978). Freshwater Carbonate Sedimentation. In: Lerman A. (eds) Lakes. Springer, New York, NY

James W. Patterson, Herbert E. Allen & John J. Scala. (1977). Carbonate precipitation for heavy metals pollutants. Water Pollution Control Federation, 49(12), 2397-2410.

M.A. Barakat. (2011). New trends in removing heavy metals from industrial wastewater. Arabian Journal of Chemistry, 4(4), 361-377.

M.N. Rao, Razia Sultana & Sri Harsha Kota. (2016). Hazardous Waste. In. Solid and hazardous waste management, Science and Engineering, Elsevier.

İlknur Demirtaş, Sezgin Bakırdere & O. YavuzAtaman. (2015). Lead determination at ng/mL level by flame atomic absorption spectrometry using a tantalum coated slotted quartz tube atom trap. Europe PMC, 138, 218-224.

doi: 10.1016/j.talanta.2015.02.044

A. Negrea, M. Ciopec, L. Lupa, C. Muntean, P. Negrea. (2008). Studies regarding the copper ions removal from waste waters. Buletinul Ştiinţific al Universităţii “Politehnica” din Timisoara, 53(67), 93-97.

Lewinski A. A. (2007). Hazardous Materials and Wastewater. In: Treatment, Removal and Analysis, (1st, ed.). New York: Nova Science Publishers.

Published
2019-11-30
How to Cite
Halid Junuzović, Sabina Begić, Amra Selimović, Abdel Đozić, Ramzija Cvrk, & Melisa Ahmetović. (2019). Efficiency of Carbonate Precipitation and Removal of Copper and Nickel Ions from their Monocomponent and Two-component Aqueous Solutions. International Journal for Research in Applied Sciences and Biotechnology, 6(6), 11-15. https://doi.org/10.31033/ijrasb.6.6.3

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