Biosorption of Lead (II) by Natural Bentonite: Adsorbent Characterization and Performance Assessment

Authors

  • Amna Karić Senior Asst., Department of Chemical Engineering, Faculty of Metallurgy and Technology, University of Zenica, BOSNIA AND HERZEGOVINA.
  • Amra Odobašić Full Prof. Dr., Department of Physical Chemistry and Electrochemistry, Faculty of Technology, University of Tuzla, BOSNIA AND HERZEGOVINA. https://orcid.org/0000-0003-1436-6698
  • Gordan Avdić Associate Prof. Dr., Department of Chemical Engineering, Faculty of Technology, University of Tuzla, BOSNIA AND HERZEGOVINA.
  • Edisa Papraćanin Assistant Prof. Dr., Department of Chemical Engineering, Faculty of Technology, University of Tuzla, BOSNIA AND HERZEGOVINA.
  • Sanja Panić Research Associate, Department of General Engineering Discipline, Faculty of Technology, University of Novi Sad, SERBIA

DOI:

https://doi.org/10.31033/ijrasb.9.2.17

Keywords:

biosorption, bentonite, characterization, lead, isotherm

Abstract

In this research, the results of bentonite characterization (pH value of bentonite suspension, point of zero charge, cation exchange capacity,  SEM, XRF, DTG) are presented. The results of lead (II) removal efficiency at initial lead (II) concentrations of 200, 300 and 400 mg/L, and biosorbent dosage of 1 gram in 50 ml of lead(II) solution,  are also presented, as well as the values of the Freundlich and Langmuir constants from the Freundlich and Langmuir adsorption isotherms. The obtained results showed that removal efficiency is high for all three examined initial lead (II) concentrations, and it is above 99%. The lead (II) removal efficiency slightly decreases with an increase in initial lead concentration. Experimental data obtained from adsorption experiment with contact time of 2.5 minutes, stirring rate 100 rpm, temperature 250C and pH value 5 are better fitted with the linearized Langmuir equation isotherm, giving an R2 value closest to unity (0.9994), than to linearized Freundlich equation (0.9886).

Downloads

Download data is not yet available.

References

Xiaoxing Zhang, Hui Liu, Jin Yang, Li Zhang, Binxia Cao, Libo Liu, and Weimin Gong (2021.). Removal of cadmium and lead from aqueous solutions using iron phosphate-modified pollen microspheres as adsorbents. Reviews on Advanced Materials Science. 60: 365–376. DOI /10.1515/rams-2021-0035.

Khan M. R., Hegde R. A., Shabiimam M. A. (2017.). Adsorption of Lead by Bentonite Clay. International Journal of Scientific Research and Management (IJSRM). Volume 5, Issue 07, Pages 5800-5804. ISSN (e): 2321-3418. DOI: 10.18535/ijsrm/v5i7.02

D.John Babu, G.Kalyani, H.Joga Rao, Y.Prasanna Kumar, P.King (2012.). Biosorption characteristics of Lead onto Bentonite Clay, as Low-cost natural biosorbent. International Journal of Scientific & Engineering Research. Volume 3, Issue 8, August-2012. ISSN 2229-5518.

Asli Baysal, Nil Ozbek and Suleyman Akman (2013.). Determination of Trace Metals in Waste Water and Their Removal Processes. Waste Water - Treatment Technologies and Recent Analytical Developments. Chapter 7, (145-171). DOI /10.5772/52025.

Ponnusamy Senthil Kumar, Subramaniam Ramalingam, Vasanthakumar Sathyaselvabala, Selvaraj Dinesh Kirupha, Arukkani Murugesan and Subramanian Sivanesan (2012.). Removal of cadmium(II) from aqueous solution by agricultural waste cashew nut shell. Korean J. Chem. Eng.(Vol. 29, No. 6), 756-768. DOI: 10.1007/s11814-011-0259-2.

Ping Xin Sheng, Yen-Peng Ting, and J. Paul Chen (2007.). Biosorption of Heavy Metal Ions (Pb, Cu, and Cd) from Aqueous Solutions by the Marine Alga Sargassum sp. in Single- and Multiple-Metal Systems. Ind. Eng. Chem. Res.. 46, 2438-2444. DOI 10.1021/ie0615786.

Jonathan Febrianto, Aline Natasia Kosasih, Jaka Sunarso, Yi-Hsu Ju, Nani Indraswati, Suryadi Ismadji (2009.). Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. Journal of Hazardous Materials. 162, 616–645. DOI: 10.1016/j.jhazmat.2008.06.042.

Jock Asanja Alexander, Muhammad Abbas Ahmad Zaini, Surajudeen Abdulsalam, Usman Aliyu El-Nafaty & Umar Omeiza Aroke (2018.). Isotherm studies of lead(II), manganese(II), and cadmium(II) adsorption by Nigerian bentonite clay in single and multimetal solutions. Particulate Science and Technology. DOI: 10.1080/02726351.2017.1404514.

Saad A. Al-Jlil (2015.). Characterization and Application of Bentonite Clay for Lead Ion Adsorption from Wastewater: Equilibrium and Kinetic Study. Research Journal of Environmental Sciences. 9(1): 1-15. DOI: 10.3923/rjes.2015.1.15.

Slađana S. Meseldžija (2021.). Removal of heavy metal ions from aqueous solutions utilizing waste lemon peel. Doctoral Dissertation, University of Belgrade, Faculty of Physical chemistry, Belgrade, Serbia.

Xiaodong Liu, Xianjun Lu (2011.). Correlation Between Bentonite’s Cation Exchange Capacity (CEC), Activated Clay Quality Indexes and Activation Strength. Applied Mechanics and Materials Vols 99-100, pp 1031-1034. DOI: 10.4028/www.scientific.net/AMM.99-100.1031.

Sheng-Fong Lo, Song-Yung Wang, Ming-Jer Tsai, Lang-Dong Lin (2012.). Adsorption capacity and removal efficiency of heavy metal ions by Moso and Ma bamboo activated carbons. Chemical Engineering Research and Design. 90, 1397–1406. DOI: 10.1016/j.cherd.2011.11.020.

Masindi Vhahangwele, Gitari W. Mugera and Ngulube Tholiso (2014.). Defluoridation of drinking water using Al3+ -modified bentonite clay: optimization of fluoride adsorption conditions. Toxicological and Environmental Chemistry. DOI: 10.1080/02772248.2014.977289.

P. Stathi, I.T. Papadas, A. Tselepidou, Y. Deligiannakis (2010.). Heavy metal uptake by a high cation-exchange-capacity montmorillonite: the role of permanent charge sites. Global NEST Journal. Vol 12, No 3, pp 248-255. DOI: 10.30955/gnj.000722.

Lorenz Paul Meier and Rolf Nüesch (1999.). The Lower Cation Exchange Capacity Limit of Montmorillonite. Journal of Colloid and Interface Science. 217, 77–85. DOI: 10.1006/jcis.1999.6254.

Marjan S. Ranđelović, Milovan M. Purenović, Aleksandra R. Zarubica, Igor D. Mladenović, Jelena M. Purenović, Milan Z. Momčilović (2011.). Physico-chemical characterization of bentonite and its application for Mn2+ removal from water. Hem. Ind. 65 (4) 381–387. DOI: 10.2298/HEMIND110322029R.

S. Al-Shahrani (2010.). Removal of lead from aqueous solutions using Saudi activated bentonite. WIT Transactions on Ecology and the Environment, Vol 135. DOI: 10.2495/WP100241.

Downloads

Published

2022-04-08

How to Cite

Karić, A., Odobašić, A., Avdić, G., Papraćanin, E., & Panić, S. (2022). Biosorption of Lead (II) by Natural Bentonite: Adsorbent Characterization and Performance Assessment. International Journal for Research in Applied Sciences and Biotechnology, 9(2), 234–242. https://doi.org/10.31033/ijrasb.9.2.17

Issue

Section

Articles